化学
催化作用
钯
镍
还原消去
联轴节(管道)
脱碳
偶联反应
有机化学
组合化学
机械工程
工程类
作者
Yunfei Peng,Ryota Isshiki,Kei Muto,Junichiro Yamaguchi
出处
期刊:Chemistry Letters
[The Chemical Society of Japan]
日期:2022-07-05
卷期号:51 (7): 749-753
摘要
Ni or Pd-catalyzed decarbonylative reductive couplings of aromatic esters were developed. A range of (hetero)aromatic esters was applicable to these reductive homocoupling reactions. Moreover, it was found that Pd-catalysis enables a reductive decarbonylative cross-coupling between two different aromatic esters to afford a nonsymmetrical biaryls system. Ni- or Pd-catalyzed decarbonylative reductive couplings of aromatic esters were developed. A range of (hetero)aromatic esters was applicable to these reductive homocoupling reactions. Moreover, it was found that Pd-catalysis enables a reductive decarbonylative cross-coupling between two different aromatic esters to afford a nonsymmetrical biaryls system.
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