吸附
扩散
动能
动力学
化学
离子交换树脂
活化能
离子交换
有效扩散系数
热力学
离子
传质
分析化学(期刊)
扩散过程
物理化学
无机化学
色谱法
有机化学
医学
放射科
创新扩散
量子力学
计算机科学
物理
知识管理
磁共振成像
作者
Jiebing Zhang,Xiubin Ren,Guangheng Wang,Xiaoli Zhang
标识
DOI:10.4236/aces.2017.74030
摘要
In order to explore internal factors for adsorption kinetic effect of miglitol by D001 resin, a batch adsorption operation for miglitol kinetic adsorption at different concentrations, temperatures and vibrating rates was investigated in oscillator (SHZ-A), respectively. The different kinetic mathematical model, Webber-Morris kinetic equation, film diffusion coefficient equation and kinetic boundary model were all applied to discuss the adsorption process. The results showed that Type 1 pseudo-second order kinetic equation can be all used to describe miglitol adsorbed by D001 resin at different concentrations, temperatures and vibrating rates. Moreover, the total activation energy (Ea) can be calculated and its value is 9.7 kJ/mol, and then calculated values of the process film diffusion coefficient and pore diffusion coefficient, it may be inferred from these gotten values that the ion exchange process is all mainly controlled by film diffusion. Therefore, the results also suggest that the external adsorption factors such as solute concentration, temperature and vibrating rate for effect of mass transfer diffusion process control of miglitol onto D001 resin are relatively weak.
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