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Development of active biocomposite films based on poly(lactic acid) and wine by‐product: Effect of grape pomace content and extrusion temperature

生物复合材料 挤压 材料科学 极限抗拉强度 乳酸 玻璃化转变 复合材料 食品科学 复合数 聚合物 化学 细菌 生物 遗传学
作者
Julio Bruna,Mario Castillo‐Ruiz,Carol López de Dicastillo,Cristina Muñoz‐Shugulí,Marcia Lira,Abél Guarda,Francisco J. Rodríguez,María José Galotto
出处
期刊:Journal of Applied Polymer Science [Wiley]
卷期号:140 (38) 被引量:8
标识
DOI:10.1002/app.54425
摘要

Abstract This work aims to evaluate the effect of the extrusion temperature of poly(lactic acid) (PLA) with different grape pomace (GP) content for the development of active biocomposite films. Two different GP concentrations (10 and 15 wt.%) were used to obtain GP/PLA composites through extrusion at three different temperature profiles. The biocomposites were characterized through optical, thermal, structural, and mechanical tests. In addition, the antimicrobial and antioxidant capacity of materials were evaluated. Results showed GP antioxidant components are stable up to 180°C. The incorporation of GP in PLA resulted in red‐color films with a high color difference (Δ E > 30). The glass transition, cold crystallization, and melting temperatures as well as the tensile strength of PLA decreased by increasing GP concentration in the films; however, elastic modulus and elongation at break increased. The biocomposite with lowest GP content had better antimicrobial activity against Escherichia coli and Listeria innocua . Contrary, 15% GP/PLA composite showed the highest antioxidant activity. Nevertheless, high extrusion temperature profile reduced the bioactivity of materials due to the GP degradation. These results showed the feasibility and best extrusion temperature profile to develop active materials using wine by‐products, which could be applied as active food packaging.
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