电子转移
苝
二亚胺
激发态
光化学
接受者
光诱导电子转移
材料科学
反应速率常数
化学
原子物理学
分子
物理
动力学
有机化学
量子力学
凝聚态物理
作者
Chamari V. Ileperuma,José Garcés‐Garcés,Shuai Shao,Fernando Fernández‐Lázaro,Ángela Sastre‐Santos,Paul A. Karr,Francis D’Souza
标识
DOI:10.1002/chem.202302817
摘要
Wide-band-capturing artificial photosynthetic model compounds featuring bisstyrylBODIPY and perylene diimide have been newly synthesized to probe excited-state energy and electron transfer. Excited-state DFT and free-energy calculations supported the occurrence of such photo events. Pump–probe spectroscopy provided the ultimate evidence wherein the measured rate constants for energy transfer were in the range of 1011 s−1, while the electron transfer rate constants were in the range of 10 s−1, thus highlighting their potential use in solar energy harvesting. More information can be found in the Research Article by F. Fernández-Lázaro, Á. Sastre-Santos, F. D'Souza et al. (DOI: 10.1002/chem.202301686).
科研通智能强力驱动
Strongly Powered by AbleSci AI