磷化氢
催化作用
区域选择性
氟
三氟甲基
化学
分子间力
组合化学
有机化学
分子
烷基
作者
Yu Mao,Yilin Liu,Xiaochen Wang,Shengyang Ni,Yi Pan,Yi Wang
标识
DOI:10.1016/j.cclet.2023.109443
摘要
This work describes intermolecular acylfluorination of gem-difluoroenynes using acyl fluorides as both acyl source and fluorine source. Trifluoromethyl-substituted allenones or furans could be selectively achieved via phosphine and silver catalysis. These approaches exhibit high regioselectivity, atom economy and broad functionality tolerance.
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