A high-performance electrocatalyst for oxygen reduction derived from copolymer-anchored polyoxometalates

The development and synthesis of cathode electrocatalysts with high activity and durable stability for metal-air batteries is an important challenge in the area of electrocatalysis. Herein, we introduce a novel in-situ nitriding and phosphating strategy for producing W 3 N 4 and WP from phosphotungstic acid (HPW)-polyaniline-phytic acid-Fe 3+ organic–inorganic hybrid material. The final material has a three-dimensional porous framework with W 3 N 4 -WP heterostructures embedded in the carbon matrix (W 3 N 4 -WP@NPC). As-made materials exhibit exceptional electrocatalytic performance for the oxygen reduction reaction (ORR), with a diffusion-limiting current density of 6.9 mA·cm −2 and a half-wave potential of 0.82 V. As a Zn-air primary cathode, the W 3 N 4 -WP@NPC assembled battery can provide a relatively high peak power density (194.2 mW·cm −2 ). As a Zn-air secondary air-cathode, it has great cycling stability over 500 h. This work provides a simple and efficient method for rationally designing high-performance air cathodes from copolymer-anchored polyoxometalates.