光催化
材料科学
氮化碳
吸收(声学)
铜
石墨氮化碳
光化学
氮化物
载流子
可见光谱
化学工程
碳纤维
催化作用
纳米技术
光电子学
化学
有机化学
复合材料
冶金
图层(电子)
复合数
工程类
作者
Zhenyu Wang,Mingyang Zhang,Jing Hu,Zhiqiang Li,Wenda Zhang,Junjun Zhang,Zhiqiang Wang,Xutao Guo,Chunliu Yan,Hongkuan Yuan,Mu-Qing Li,Yingzhi Li,Xiao Wei Sun,Zhenghe Xu,Shien‐Ping Feng,Zhouguang Lu
标识
DOI:10.1016/j.jpowsour.2023.233188
摘要
CO2 photocatalytic conversion has been considered as a promising strategy to reduce CO2 level and produce chemical feedstocks. However, developing highly efficient photocatalysts still remains a challenge. Here, copper (Cu) single atom sites (SAs) have been loaded into polymeric carbon nitride (CN) framework through one-step thermal polymerization method. The Cu sites loaded in CN framework can not only enhance the visible light absorption, but also accelerate the mobility of charge carriers. The range of light absorption can be extended to a longer wavelength, and the recombination of photogenerated electron and hole pairs can be considerably suppressed. Furthermore, the valence band of obtained photocatalysts shift more negative with Cu loading, resulting in stronger reduction potential for CO2 photocatalytic conversion. As a result, the CO2 photocatalytic activity can be considerably enhanced a lot. By regulating the content of Cu, the CO production amount (1.62 μmol/g.h) can be enhanced 2.7 times higher than that of bulk CN (0.6 μmol/g.h). This work proposes a facile and eco-friendly way to modify CN photocatalyst, which is inspiring to design high efficiency photocatalysts.
科研通智能强力驱动
Strongly Powered by AbleSci AI