化学
尖晶石
发光
微观结构
燃烧
兴奋剂
镁
铝酸盐
晶体结构
物理化学
热力学
化学工程
冶金
结晶学
凝聚态物理
有机化学
光电子学
材料科学
水泥
工程类
物理
作者
Mehran Ghodrati,Seyed Mahdi Rafiaei
标识
DOI:10.1002/jccs.202400155
摘要
Abstract In the current research, the rare earth‐doped magnesium aluminate (MgAl 2 O 4 :Eu 3+ ) spinels were produced by the combustion synthesis method. The employment of thermodynamic calculations revealed that the combustion approach is a proper way to synthesize MgAl 2 O 4 :Eu 3+ material by urea fuel, although this procedure was fulfilled at 500°C, the final temperature will be around 2030°C. The x‐ray and FT‐IR spectra confirmed the successful formation of spinels, while it was shown that the calcination procedure results in a significant increase of crystallinity. On the other hand, it was interestingly seen that the addition of large amounts of Eu 3+ dopant (10 wt%) suppresses the crystallinity. The MAUD calculations interestingly revealed that the increase of Eu 3+ dopant from 1 to 10 wt% leads to the increase of MgO and Al 2 O 3 impurities. The related microstructural evaluations revealed that the particle size of the synthesized powders is mostly less than 40 nm which shows the superiority of combustion synthesis over other commercial methods. Also, the broadening of XRD peaks confirmed the formation of nano‐sized powder. The photoluminescence (PL) characterizations showed that doping of MgAl 2 O 4 with 7 wt% Eu 3+ brings the most intensive emission properties at the wavelengths of 592 and 617 nm.
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