质子
细菌视紫红质
质子输运
质子交换膜燃料电池
化学
金属有机骨架
纳米技术
电导率
氨基酸
导电体
组合化学
材料科学
膜
有机化学
物理化学
催化作用
吸附
物理
复合材料
量子力学
生物化学
作者
Xiao-Min Li,Junchao Jia,Danting Yang,Jiali Jin,Junkuo Gao
标识
DOI:10.1016/j.cclet.2023.108474
摘要
Construction of proton transport channels in metal-organic frameworks (MOFs) with simple synthesis processes, high proton conductivities and good performance stabilities has been of great interest for proton exchange membrane fuel cell (PEMFC). Herein, we mimic the proton transport behavior of amino acid residues in bacteriorhodopsin, select UiO-66-COOH as the host, glycine and aspartic acid as the functional guest molecules, and then functionalize the MOF framework with amino acids to obtain biomimetic proton transport channels. This strategy endows UiO-66-COOH-Asp a high proton conductivity of 1.19 × 10−2 S/cm at 70 °C and 98% RH, excellent cycle stability of performances and performance durability, which can be comparable to the reported MOFs-based proton conductors. Moreover, the proton conduction mechanism in UiO-66-COOH-Asp is elaborated in detail due to its visual structure, which is also one of the advantages of adopting MOFs as research platform, making it possible to optimize the structure-activity relationship of advanced materials. Notably, this strategy has clear objectives and simple synthesis, which has made certain contributions to both theoretical research and future industrial production of proton conductors.
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