Synthesis and Characterisation of Various Diester and Triester Adducts of TiCl4

Abstract Titanium(IV) chloride and the triester glycerol tribenzoate (gtb) were reacted under moisture‐free conditions in order to investigate the use of triester‐containing oils in the purification of TiCl 4 in industrial processes. This resulted in the isolation of a chloro‐bridged dimeric complex containing four titanium centres [{(TiCl 4 ) 2 (gtb)} 2 ] ( 1 ). Further novel coordination compounds of TiCl 4 and the diesters; diisopropyl malonate, dibenzyl malonate and diethyl succinate were synthesised by direct reaction under moisture‐free conditions, yielding [TiCl 4 {CH 2 (COO i Pr) 2 }] ( 2 ), [TiCl 4 {CH 2 (COOCH 2 Ph) 2 }] ( 3 ) and [TiCl 4 {C 2 H 4 (COOEt) 2 }] ( 4 ) respectively. The structures of compounds 1 – 4 were determined by single‐crystal X‐ray diffraction. All structures assumed an octahedral geometry consisting of the titanium bound to four chloride ligands and the diester molecule acting as a bidentate ligand, through its two carbonyl oxygen atoms. Exposure of the isopropyl malonate reaction to trace amounts of water during synthesis resulted in the formation of an oxo‐bridged dimeric structure [Ti 2 (μ‐O)Cl 3 {CH 2 (COO i Pr) 2 } 2 ] ( 2b ), the structure of which was also obtained via single‐crystal X‐ray diffraction.