Zeolitic-imidazolate framework (ZIF-67) based bipolar memristor for nonvolatile ReRAM application

In the realm of next-generation nonvolatile memories, there is a strong demand for resistive random access memory (ReRAM) devices that are affordable, stable, and simple to produce. Metal–organic frameworks (MOFs) have garnered extensive research attention across diverse fields due to their remarkable chemical adaptability, stability, and exceptional structural variability. In this work, a ReRAM device has been fabricated that incorporates a solution-processed thin film of zeolitic imidazolate framework (ZIF-67), a material of MOFs class, as the resistive switching (RS) layer. This Al/ZIF-67/ITO structured device possesses a consistent RS behavior with a high on/off resistance ratio of ∼104. The retention of low resistance state and high resistance state have been shown up to 104 s. Furthermore, the device also shows a consistent switching for 500 cycles of pulse switching signals of +6 V/−1.8 V (set/reset). Based on the impedance spectroscopy analysis, a filamentary switching mechanism has been established for the RS behavior of the device. The robust and enduring performance, coupled with the substantial on/off resistance ratio and high retention of the states, makes this device a promising candidate for nonvolatile ReRAM applications.