Hybrid NenG/ZSM‐5 Towards Highly Selective and Efficient Photocatalysis for Generation of Leucodopaminechrome and Gluconic Acid Under Solar Light

Abstract Glucose, an abundant and renewable form of biomass, has garnered significant attention in research for its conversion into high‐value chemicals such as gluconic acid. Traditional methods for biomass transformation typically involve high energy input, elevated temperature, pressure, and costly systems. In contrast, photocatalysis emerges as a promising approach to produce organic molecules under mild conditions, harnessing energy from natural sunlight or lamps. This study presents the nitrogen‐enriched graphene with zeolite second Mobil–5 (N en G/ZSM‐5) photocatalyst, evaluated for generating high‐value chemicals (gluconic acid and leucodopaminechrome) under solar light irradiation. The N en G/ZSM‐5 photocatalyst, synthesized from nitrogen‐doped graphene and ZSM‐5, successfully converted dopamine into leucodopaminechrome (71.54 %) — a critical step in dopamine regeneration and transformed glucose into gluconic acid (85 %). The addition of ZSM‐5 to N en G provided stability and enhanced product selectivity. The outstanding performance of the N en G/ZSM‐5 photocatalyst can be attributed to its heightened solar light harvesting potential, appropriate energy band gap, and uniformly arranged π‐electron channels. This research focuses on solar conversion of glucose to gluconic acid and dopamine regeneration, with potential for further exploration in the research domain.