八面体
傅里叶变换红外光谱
电化学
碱性电池
化学
红外线的
锰
电解质
分析化学(期刊)
傅里叶变换
红外光谱学
无机化学
失真(音乐)
材料科学
结晶学
电极
晶体结构
物理化学
光学
有机化学
光电子学
物理
放大器
量子力学
CMOS芯片
作者
M.V. Ananth,Sushama Pethkar,K. Dakshinamurthi
标识
DOI:10.1016/s0378-7753(98)00100-1
摘要
Infrared fourier transform (FTIR) spectroscopic analysis of four commercial manganese dioxides having applications in alkaline batteries is reported. These samples of different alkaline activity have Nstutite or γ-MnO2 as the major phase. With respect to the interaction of Mn with OH− and other groups, the development of weak bands around 1363 cm−1 represents the variation in discharge performance. Significant changes are seen in the MnO6 octahedral arrangement from sample to sample by examining the spectra in low-frequency regions. Distortion of MnO6 octahedra by the constituent water promotes the electrochemical behaviour. In general, the alkaline electrochemical activity of Nstutite MnO2 samples can be understood from their infrared spectra.
科研通智能强力驱动
Strongly Powered by AbleSci AI