TiO2 photocatalyst supported on titanium was used in the study of nitrobenzene degradation.The influence factors of photocatalysis time and pH were studied.The experiment indicated that the optimum conditions were pH=3 and photocatalysis time 100 min.The results would be better to treat the low nitrobenzene wastewater with H2O2+UV+TiO2 photocatalysis reaction system.