渡线
过冷
亚稳态
甘油
扩散
化学
材料科学
爱因斯坦
化学物理
统计物理学
热力学
物理
粘度
经典力学
有机化学
人工智能
计算机科学
作者
Francesco Mallamace,Carmelo Corsaro,Domenico Mallamace,Sebastiano Vasi,C. Vasi,H. Eugene Stanley
摘要
We study the self-diffusion coefficient and viscosity of a water-glycerol mixture for several glycerol molar fractions as a function of temperature well inside the metastable supercooled regime. We perform NMR experiments and verify that the system has at different concentration a fragile-to-strong crossover accompanied by the violation of the Stokes-Einstein relation. We observe that the crossover temperature depends on the water amount. Studying the fractional representation of the Stokes-Einstein relation, we find that in these systems dynamical arrest does not exhibit criticality and the transport parameters have a universal behavior.
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