Lewis acid–base adducts of Al(N(C 6 F 5 ) 2 ) 3 and Ga(N(C 6 F 5 ) 2 ) 3 – structural features and dissociation enthalpies

Herein we present the molecular structures of six neutral Lewis acid–base adducts of the Lewis superacid Al(N(C 6 F 5 ) 2 ) 3 and its higher homolog Ga(N(C 6 F 5 ) 2 ) 3 with the electron pair donors MeCN, CN t Bu, THF and PMe 3 .