有孔小珠
文石
拉曼光谱
矿物学
氧化锡
发色团
材料科学
地质学
考古
方解石
化学
分析化学(期刊)
氧化物
光学
冶金
复合材料
物理
色谱法
地理
有机化学
作者
Noémi Fischbach,Anh‐Tu Ngo,Philippe Colomban,Martial Pauly
出处
期刊:Archéosciences
[OpenEdition]
日期:2016-01-01
卷期号:40: 83-102
被引量:21
标识
DOI:10.4000/archeosciences.4774
摘要
About hundred out of three hundred colored beads excavated from the necropolis of Antsiraka Boira (AB), in Mayotte Island (12-13th c.) were classified according to Wood’s morphological criteria and studied with a portable Raman spectrometer (532nm). Based on the recorded spectra, 22 beads were identified as representative and further analyzed in the laboratory with High-Resolution Raman spectrometers, using wavelengths of 458, 633 and 785nm. Additional SEM-EDS analysis was carried out on the surface and, sometimes, the bead cross-section. It turns out that white beads are made of aragonite and that almost all other beads have a soda glass matrix. Pyrochlore (yellow), amber/“Fe-S” (black), manganese oxide (black), copper metal nanoparticles (red), and Cu2+ ions (turquoise) chromophores were identified. Some red, yellow, black and turquoise beads also show the signature of chromium-doped tin sphene that could therefore be used as a marker. Most beads from the AB site can be classified as “Indo-Pacific”, revealing a similarity with the contemporary South African site of K2 (close to Mapungubwe). However, some red and black beads are similar to molten ceramic beads from the Vohemar Islamic necropolis (13-17th century AD, Madagascar Island). The on-site Raman analysis appears sufficient for the identification of chromophores and glass types.
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