A Janus Fe‐SnO2Catalyst that Enables Bifunctional Electrochemical Nitrogen Fixation

Abstract Electrochemical N2reduction reactions (NRR) and the N2oxidation reaction (NOR), using H2O and N2, are a sustainable approach to N2fixation. To date, owing to the chemical inertness of nitrogen, emerging electrocatalysts for the electrochemical NRR and NOR at room temperature and atmospheric pressure remain largely underexplored. Herein, a new‐type Fe‐SnO2was designed as a Janus electrocatalyst for achieving highly efficient NRR and NOR catalysis. A high NH3yield of 82.7 μg h−1 mgcat.−1and a Faraday efficiency (FE) of 20.4 % were obtained for NRR. This catalyst can also serve as an excellent NOR electrocatalyst with a NO3−yields of 42.9 μg h−1 mgcat.−1and a FE of 0.84 %. By means of experiments and DFT calculations, it is revealed that the oxygen vacancy‐anchored single‐atom Fe can effectively adsorb and activate chemical inert N2molecules, lowering the energy barrier for the vital breakage of N≡N and resulting in the enhanced N2fixation performance.