非阻塞I/O
电致变色
氧化镍
X射线光电子能谱
氨
材料科学
化学浴沉积
电化学
化学工程
水溶液
镍
沉积(地质)
透射率
微观结构
无机化学
薄膜
纳米技术
电极
化学
冶金
有机化学
物理化学
催化作用
古生物学
工程类
生物
光电子学
沉积物
作者
Jonghan Yu,Sang-Hun Nam,Yeong Eun Gil,Jin‐Hyo Boo
标识
DOI:10.1016/j.apsusc.2020.147441
摘要
This paper presents the electrochromic (EC) characteristics of nickel oxide (NiO) nanoflakes array prepared by chemical bath deposition (CBD) method with different ammonia concentration. Prepared NiO films have porous structure with 2-dimensionally networked nanoflake arrays. The addition of aqueous ammonia significantly affects the growth of NiO film. Moreover, appropriate amount addition of aqueous ammonia is important in obtaining a balanced EC performance of NiO films between transmittance modulation and cycling durability. Excess concentration of ammonia cause not only a decrease in the thickness of NiO films but also change the growth direction of flakes. XPS results present that high concentration of ammonia could induce the peak shifting toward the low binding energy, which attributed from initial state effect between nickel and oxygen, which is substituted by nitrogen. The best electrochemical durability at 550 nm was achieved for NiO-25 film with high transmittance modulation (Tbleaching: 86.8% and Tcoloring: 23.4%) and noticeable cycling stability (only 25% decrease after 5000 cycles).
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