吸附
介孔材料
巴(单位)
变压吸附
锆
金属有机骨架
材料科学
空气分离
解吸
化学工程
沸石
选择性
高压
金属
环境压力
化学
有机化学
催化作用
热力学
氧气
冶金
气象学
工程类
物理
作者
Min Bum Kim,Tea Hoon Kim,Tae Ung Yoon,Jo Hong Kang,Jeong Hoon Kim,Yang˗Seop Bae
标识
DOI:10.1016/j.jiec.2019.12.032
摘要
Adsorptive separation of SF6/N2 mixtures is an important issue since SF6 is a significant greenhouse gas. Although separation performances should be evaluated under high pressure conditions to find an efficient adsorbent candidate for pressure swing adsorption (PSA) processes, no studies on metal–organic frameworks (MOFs) have focused on SF6/N2 separation at high pressures above 1 bar. In this study, we evaluated the potential of three hydrothermally stable adsorbents, including two MOFs (UiO-66 and UiO-67) and zeolite-13X, for SF6/N2 separation under normal PSA operation pressures (∼10 bar). Interestingly, UiO-67 with a high surface area and large pore size exhibited very high SF6/N2 selectivity (30∼37) at 10 bar as well as a significantly large SF6 working capacity (5.94 mmol g−1) between 10 bar and 1 bar. Moreover, UiO-67 showed facile regeneration at the ambient temperature as well as good cyclic adsorption and desorption behavior during 20 cycles. These results show that UiO-67 is a potential adsorbent for adsorptive SF6/N2 separation.
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