Siderite's green revolution: From tailings to an eco-friendly material for the green economy

Siderite, extensively mined as a natural iron mineral, is often discarded as tailings due to the low grade of the ore and due to the high cost of current sorting technologies. Yet, this mineral has demonstrated significant potential in several pivotal areas of the environmental remediation. Siderite not only possesses exceptional adsorption, catalytic, and microbial carrier capabilities but also offers an eco-friendly and cost-effective solution for the environmental pollution management. This article consolidates research advancements and achievements over the past few decades concerning siderite's role in pollution control, delving deeply into its various remediation pathways. Initially, the paper contrasts the performance differences between natural and synthetic siderite, followed by a comprehensive overview of siderite's adsorption mechanisms for various inorganic pollutants. Furthermore, this paper analyzes the unique physicochemical attributes of siderite as both, a reductant and the catalyst, with a special emphasis on its use in the preparation of SCR catalysts and in the catalytic advanced oxidation processes for organic pollutants' degradation. This paper also enumerates and discusses the myriad advantages of siderite as a microbial carrier, thereby enhancing our understanding of biogeochemical cycles and pollutant transformations. In essence, this review systematically elucidates the mechanisms and intrinsic physicochemical properties of siderite in pollution control, paving the way for novel strategies to augment siderite's environmental remediation performance.