化学
吡咯
催化作用
氮气
三环
组合化学
有机化学
作者
Linfei Wang,Renhua Fan
出处
期刊:Organic Letters
[American Chemical Society]
日期:2012-07-10
卷期号:14 (14): 3596-3599
被引量:32
摘要
The oxidative dearomatization of para-substituted o-alkynylanilines afforded 2-alkynyl cyclohexadienimines, which can act as active substrates for reaction with electron-rich styrenes. The reaction is metal-controlled. Bi(OTf)3-catalyzed reactions afforded 3,4-dihydro-cyclopenta[c,d]indoles, and AgOTf-catalyzed reactions provided tricyclic pyrrole derivatives.
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