Meeting the Challenge of Intermolecular Gold(I)‐Catalyzed Cycloadditions of Alkynes and Allenes

The development of gold(I)-catalyzed intermolecular carbo- and hetero-cycloadditions of alkynes and allenes has been more challenging than their intramolecular counterparts. Here we review, with a mechanistic perspective, the most fundamental intermolecular cycloadditions of alkynes and allenes with alkenes.