渗透
聚二甲基硅氧烷
膜
材料科学
渗透
选择性
气体分离
复合材料
图层(电子)
多孔性
化学工程
磁导率
聚合物
复合数
化学
有机化学
生物化学
工程类
催化作用
作者
Roman Selyanchyn,Miho Ariyoshi,Shigenori Fujikawa
出处
期刊:Membranes
[MDPI AG]
日期:2018-12-02
卷期号:8 (4): 121-121
被引量:44
标识
DOI:10.3390/membranes8040121
摘要
The effect of thickness in multilayer thin-film composite membranes on gas permeation has received little attention to date, and the gas permeances of the organic polymer membranes are believed to increase by membrane thinning. Moreover, the performance of defect-free layers with known gas permeability can be effectively described using the classical resistance in series models to predict both permeance and selectivity of the composite membrane. In this work, we have investigated the Pebax®-MH1657/PDMS double layer membrane as a selective/gutter layer combination that has the potential to achieve sufficient CO₂/N₂ selectivity and permeance for efficient CO₂ and N₂ separation. CO₂ and N₂ transport through membranes with different thicknesses of two layers has been investigated both experimentally and with the utilization of resistance in series models. Model prediction for permeance/selectivity corresponded perfectly with experimental data for the thicker membranes. Surprisingly, a significant decrease from model predictions was observed when the thickness of the polydimethylsiloxane (PDMS) (gutter layer) became relatively small (below 2 µm thickness). Material properties changed at low thicknesses-surface treatments and influence of porous support are discussed as possible reasons for observed deviations.
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