材料科学
X射线光电子能谱
碳纳米管
检出限
傅里叶变换红外光谱
循环伏安法
扫描电子显微镜
分析化学(期刊)
电化学气体传感器
镍
化学工程
电极
电化学
核化学
纳米技术
化学
复合材料
色谱法
冶金
物理化学
工程类
作者
Weiye Zhang,Siqing Ye,Yu Wei Diao,Xiujun Deng,Weili Li,Hongxing He,Qian Liu,Guangzhi Hu
标识
DOI:10.1016/j.mtchem.2023.101863
摘要
Magnetic multi-walled carbon nanotubes (Fe3O4@MWCNTs) were synthesized utilizing a solvothermal technique in this study, followed by the synthesis of Ni(II)-imprinted polymers (IIP) using a surface imprinting technique in this study. The materials' morphologies, structures, and chemical compositions were characterized using several techniques: Fourier transform infrared spectroscopy (FT-IR), Brunauer-Emmett-Teller (BET) analysis, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). The IIP was loaded onto a carbon-paste electrode using differential pulsed anodic solution voltammetry (DPASV) to form an electrochemical sensor (IIP-CPE) that could effectively identify Ni(II). The effects of the electrode composition, solution pH, deposition potential, and deposition time on the response of the IIP-CPE electrochemical sensor to Ni(II) peak currents were also investigated. The IIP-CPE demonstrated secondary linearity within the concentration ranges of 0.5–20 μg/L and 20–200 μg/L for Ni(II), with a detection limit of 0.27 μg/L under optimized conditions. It also maintained good selectivity, anti-interference, reproducibility, and stability and showed good accuracy in actual water samples. The constructed IIP-CPE has promising applications for the rapid monitoring trace-level Ni(II) in water bodies.
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