山梨醇酐
催化作用
化学
铱
有机化学
组合化学
脂肪酸
脂肪酸
作者
Lucie Grand,Powderly Marian,Florence Popowycz,Maïwenn Jacolot
标识
DOI:10.1021/acs.joc.2c02827
摘要
The regio- and diastereoselective synthesis of chiral amines derived from 1,4-d-sorbitan has been developed via the borrowing hydrogen reaction using a cooperative catalysis between an achiral iridium catalyst and diphenylphosphoric acid. The different reactivities of the four hydroxyl groups on the 1,4-d-sorbitan scaffold have also been highlighted.
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