聚氨酯
聚丁二烯
异氰酸酯
材料科学
高分子化学
极限抗拉强度
聚合物
复合材料
高分子科学
共聚物
作者
Ningning Liu,Minghao Zhang,Rongjie Yang,Bingyu Wang,Yang Wei,Fuzi Yang,Min Xia,Yunjun Luo
摘要
Abstract Intrinsic self‐healing materials have drawn great interest in recent years. The design of novel building blocks is essential for developing polymer networks with different properties. Allophanate is usually regarded as a side product during the preparation of polyurethanes. During the research of self‐healing polyurethane networks, we have studied the terminal functionalization of hydroxyl‐terminated polybutadiene with furfuryl isocyanate and occasionally obtained the furan‐terminated polybutadiene allophanate. The tetra‐branched molecule is employed as the crosslinker in the construction of a series of Diels–Alder type polyurethane networks. These polyurethane networks exhibit good mechanical performance and excellent self‐healing ability. Damages can be healed via the thermo‐promoted dissociation and recombination cycle, giving good to excellent recovery of tensile strength within three cycles of “damage‐repair” processes.
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