苯甲醛
苯乙烯
催化作用
过渡金属
同种类的
化学
动能
催化氧化
相(物质)
液相
氧化还原
金属
化学工程
无机化学
有机化学
共聚物
热力学
聚合物
工程类
物理
量子力学
作者
Soyeb Pathan,Anjali Patel
摘要
Mono-transition-metal-substituted phosphomolybdates, PMo11M (M = Co, Mn, Ni), were synthesized and characterized by various physicochemical techniques. They were efficiently used for liquid-phase nonsolvent oxidation of styrene under mild reaction conditions. It was found that all of the catalysts are efficient in achieving higher conversions with high turnover numbers and are selective toward benzaldehyde. A detailed kinetic study was also carried out. Although all of the catalysts are homogeneous under the present oxidation conditions, they were regenerated and reused for up to two cycles.
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