环丁砜
循环伏安法
介电谱
电解质
线性扫描伏安法
锂(药物)
阳极
电化学
阴极
X射线光电子能谱
石墨
材料科学
分析化学(期刊)
无机化学
化学
化学工程
复合材料
医学
电极
有机化学
物理化学
内分泌学
工程类
溶剂
作者
Hao Cai,Haoran Jing,Xianling Zhang,Ming Shen,Qi Wang
出处
期刊:Journal of The Electrochemical Society
[The Electrochemical Society]
日期:2017-01-01
卷期号:164 (4): A714-A720
被引量:31
摘要
Sulfolane (SL) is investigated as an electrolyte additive for LiNi1/3Co1/3Mn1/3O2/ graphite cell cycled in the voltage range of 3.0–4.6 V (vs. Li+/Li). The cyclic stability of LiNi1/3Co1/3Mn1/3O2/graphite cells is improved by using 2 vol.% SL. Charge–discharge tests on graphite/Li and LiNi1/3Co1/3Mn1/3O2/Li cells show that the cyclic improvement of the full cell results from the contribution of SL on the enforced stability of both graphite anode and LiNi1/3Co1/3Mn1/3O2 cathode. Linear sweep voltammetry data indicate that SL can improve the oxidation potential of the reference electrolyte, that is, 1.0 M LiPF6 in ethylene carbonate/dimethyl carbonate (1/1, by volume). Cyclic voltammetry, electrochemical impedance spectroscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy indicate that an SL-containing electrolyte is likely to form low impedance, as well as a protective and stable film on both cathode and anode electrodes, which improves the stability of the electrode and electrolyte during cycling.
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