丙酸
化学
结晶学
氢键
分子
立体化学
中心(范畴论)
有机化学
作者
Jianguo Wang,Yuan Zhang,Zhong-Xing Su,Xiang Liu
标识
DOI:10.1107/s1600536812014730
摘要
In the title compound, [Cd(NCS)(2)(C(4)H(6)N(4)O(2))(2)](n), the Cd(II) cation is located on an inversion center and is coordinated by two N and two S atoms from four SCN(-) anions and two N atoms from two 3-(1H-tetra-zol-1-yl)propanoic acid (Htzp) ligands in a distorted octa-hedral geometry. The SCN(-) anions bridge the Cd(II) cations into a layer structure parallel to (100). A weak intra-molecular C-H⋯N inter-action occurs. The layers are further assembled into a three-dimensional supra-molecular structure via classical O-H⋯O hydrogen bonds.
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