化学
卤素
卤化
过氧化物
药物化学
群(周期表)
序列(生物学)
有机化学
烷基
生物化学
作者
Ivan A. Yaremenko,Yulia Yu. Belyakova,Arina A. Demina,Peter S. Radulov,Igor V. Alabugin,Alexander O. Terent’ev
标识
DOI:10.1002/adsc.202300881
摘要
A selective reaction of bridged ozonides with Fe(II) salts proceeds through the sequence of O‐O, C‐C scissions and halogenation to form α‐halogen substituted δ‐ketoesters and δ‐diketones in 15‐72% yields. The overall sequence shows how a temporary installation of a peroxide functionality can be used to replace the acyl group within an acetoacetic ester unit with a halogen.
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