Preparation and characterization of cellulose fluorescent material: Experiment and simulation

The extensive use of fossil based materials has caused serious pollution problems, the full utilization of biomass resources to prepare high value-added new materials is of great significance for the environmental protection and sustainable social development. For this purpose, this study explored the preparation process and molecular dynamics simulation of cellulose fluorescent materials. Firstly, bacterial cellulose was dissolved in a solution of NaOH and urea at low temperature, followed by a solution blending and hot pressing with hyperbranched polyamide. It was found that the addition of hyperbranched polyamide could effectively filled in the internal pores of cellulose hydrogel, thereby enhancing the fluorescence effects and tensile properties, especially the elongation at break of cellulose materials. The optimal amount of hyperbranched polyamide added was 5 wt%. Molecular dynamics simulation showed that the hydrogen bonds and interaction with cellulose increased as the concentration of hyperbranched polyamide increased.