锰
化学工程
无机化学
X射线光电子能谱
隐锰铁矿
氧化还原
吸附
作者
Huiyu Zhang,Xianming Zheng,Tongzhou Xu,Pengyi Zhang
标识
DOI:10.1021/acsami.1c01433
摘要
Room-temperature catalytic decomposition of low-concentration volatile organic compounds (VOCs) in indoor air is an exciting dream to solve their pollution. Herein, two kinds of rare-earth elements (Y and La) were separately doped into birnessite-type MnO2 nanosheets in the form of single atoms by the hydrothermal method. As-synthesized La/MnO2 achieved 100% removal of 10 ppm toluene at 40 °C under the gas hourly space velocity of 60 L g-1 h-1, which was even somewhat better than the single Pt atom-doped MnO2. In addition, La/MnO2 showed the good durability at room temperature for 0.5 ppm toluene removal under the GHSV of 300 L g-1 h-1 and could be effectively regenerated at 105 °C. GC/FID, online-MS and TD-GC/MS analysis demonstrated that only ignorable trace benzene (∼3.4 ppb, < one thousandth of inlet toluene) was generated in the gas phase during catalytic decomposition of 10 ppm toluene at room temperature. This research sheds light on the development of low cost and high activity catalysts for low-concentration VOC oxidation at room temperature.
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