化学
阿扑啡
二恶英
立体化学
生物碱
传统医学
有机化学
医学
烷基
卤素
作者
Jing‐Hua Yang,Liang Li,Yun‐Song Wang,Jingfeng Zhao,Hongbin Zhang,Shi‐De Luo
标识
DOI:10.1002/hlca.200590188
摘要
Abstract Chemical examination of the BuOH extract of the leaves and twigs of Litsea glutinosa collected from Xishuangbanna resulted in the isolation of two new aporphine alkaloids, namely litseglutine A ( 1 ) and B ( 2 ), along with two known aporphine alkaloids, boldine ( 3 ) and laurolitsine ( 4 ). The structures of the new alkaloids have been elucidated on the basis of spectra analysis as 6‐demethyl‐9‐methoxy‐1,2‐(methylenedioxy)aporphin‐10‐ol (=6,7,7a,8‐tetrahydro‐10‐methoxy‐5 H ‐benzo[ g ]‐1,3‐benzodioxolo[6,5,4‐ de ]quinolin‐11‐ol; 1 ) and 1,10,11‐trimethoxyaporphin‐2‐ol (=5,6,6a,7‐tetrahydro‐1,10,11‐trimethoxy‐6‐methyl‐4 H ‐dibenzo[ de , g ]quinolin‐2‐ol; 2 ).
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