多孔性
铑
催化作用
氢甲酰化
材料科学
聚合
三苯基膦
化学工程
高分子化学
化学
有机化学
复合材料
聚合物
工程类
作者
Qi Sun,Miao Jiang,Zhenju Shen,Yinying Jin,Shuxiang Pan,Liang Wang,Xiangju Meng,Wangzhi Chen,Yunjie Ding,Jixue Li,Feng‐Shou Xiao
摘要
We reported a universal route for synthesizing porous organic ligands (POLs) via solvothermal polymerization. The POLs were obtained quantitatively, showing high surface area, large pore volume, hierarchical porosity, and superior stability. The POL bearing a triphenylphosphine supported rhodium catalyst (Rh/POL-PPh3) exhibits high activity and excellent recyclability in 1-octene hydroformylation.
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