能量转换效率
材料科学
色素敏化染料
太阳能电池
共轭体系
开路电压
介孔材料
噻吩
短路
半导体
聚合物太阳能电池
光化学
光电子学
聚合物
化学工程
纳米技术
电压
化学
有机化学
电极
物理化学
催化作用
复合材料
物理
量子力学
工程类
电解质
作者
Sang Hyuk Im,Choong Sun Lim,Jeong Ah Chang,Yong Hui Lee,Nilkamal Maiti,Hi Jung Kim,K. Nazeeruddin,Michaël Grätzel,Sang Il Seok
出处
期刊:Nano Letters
[American Chemical Society]
日期:2011-10-04
卷期号:11 (11): 4789-4793
被引量:244
摘要
Sb2S3-sensitized mesoporous-TiO2 solar cells using several conjugated polymers as hole-transporting materials (HTMs) are fabricated. We found that the cell performance was strongly correlated with the chemical interaction at the interface of Sb2S3 as sensitizer and the HTMs through the thiophene moieties, which led to a higher fill factor (FF), open-circuit voltage (Voc), and short-circuit current density (Jsc). With the application of PCPDTBT (poly(2,6-(4,4-bis-(2-ethylhexyl)-4H-cyclopenta[2,1-b;3,4-b′]dithiophene)-alt-4,7(2,1,3-benzothiadiazole)) as a HTM in a Sb2S3-sensitized solar cell, overall power conversion efficiencies of 6.18, 6.57, and 6.53% at 100, 50, and 10% solar irradiation, respectively, were achieved with a metal mask.
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