Ultrafast atomic view of laser-induced melting and breathing motion of metallic liquid clusters with MeV ultrafast electron diffraction

Significance Intense lasers can be used to drive materials into transient states far from equilibrium. Investigations of such states and processes at the atomic scale are of fundamental significance in understanding a material’s behavior under extreme conditions. Herein, an ultrafast electron diffraction technique is used to track the atomic pathway of the entire melting process of aluminum and reveal a coherent breathing motion of polyhedral clusters in transient liquid aluminum at high temperature and high pressure. The negative expansion behavior of interatomic distances in a superheated liquid state upon heating is observed. These findings provide insight into ultrafast structural transformations and transient atomic dynamics under extreme conditions.