过冷
缩放比例
玻璃化转变
放松(心理学)
长度刻度
分子动力学
材料科学
比例(比率)
BETA(编程语言)
化学物理
统计物理学
热力学
凝聚态物理
物理
核磁共振
机械
计算机科学
数学
心理学
社会心理学
量子力学
程序设计语言
聚合物
几何学
作者
Smarajit Karmakar,Chandan Dasgupta,Srikanth Sastry
标识
DOI:10.1103/physrevlett.116.085701
摘要
Temporal relaxation of density fluctuations in supercooled liquids near the glass transition occurs in multiple steps. Using molecular dynamics simulations for three model glass-forming liquids, we show that the short-time β relaxation is cooperative in nature. Using finite-size scaling analysis, we extract a growing length scale associated with beta relaxation from the observed dependence of the beta relaxation time on the system size. We find, in qualitative agreement with the prediction of the inhomogeneous mode coupling theory, that the temperature dependence of this length scale is the same as that of the length scale that describes the spatial heterogeneity of local dynamics in the long-time α-relaxation regime.
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