检出限
电极
堆积
木犀草素
材料科学
电化学
选择性
纳米技术
电化学气体传感器
化学
催化作用
色谱法
有机化学
物理化学
抗氧化剂
槲皮素
作者
Feng Gao,Weihua Hong,Tao Yang,Chenhui Qiao,Jingjia Li,Xu Xiao,Ziying Zhao,Chao Zhang,Junyuan Tang
标识
DOI:10.1016/j.jcis.2023.09.091
摘要
Although there have been advancements in electrochemical catalysts for luteolin detection, their practical use is constrained by low sensitivity, inadequate selectivity, and unsatisfactory limit of detection. MXene, a class of 2D materials, possesses exceptional physical–chemical properties that make it highly suitable for electrochemical detection. Nevertheless, the self-stacking and limited interlayer spacing of MXene impede its extensive application in electrochemical detection. Herein, a SnO2 QDs-MXene composite is synthesized for selective electrochemical detection of luteolin. Inserting SnO2 QDs between tightly stacked MXene layers expands the d-spacing of MXene, enhancing the specific surface area and enabling abundant active sites for redox reactions. The inclusion of MXene in the modified SnO2 QDs-MXene/GCE electrode significantly enhances electron transfer. As a result, the electrode demonstrates exceptional luteolin detection capabilities, including a wide linear range (0.1–1200 nM), high sensitivity (12.4 μA μM−1), and an ultra-low limit of detection (0.14 nM). Additionally, the SnO2 QDs-MXene/GCE electrode exhibits good repeatability, excellent reproducibility, remarkable stability, and high selectivity, making it suitable for practical sample analysis. This research contributes to advancing ultra-low limit of detection sensors for accurate luteolin detection.
科研通智能强力驱动
Strongly Powered by AbleSci AI