Insight into typical photo-assisted AOPs for the degradation of antibiotic micropollutants: Mechanisms and research gaps

Due to the incomplete elimination by traditional wastewater treatment, antibiotics are becoming emerging contaminants, which are proved to be ubiquitous and promote bacterial resistance in the aquatic systems. Antibiotic pollution has raised particular concerns, calling for improved methods to clean wastewater and water. Photo-assisted advanced oxidation processes (AOPs) have attracted increasing attention because of the fast reaction rate, high oxidation capacity and low selectivity to remove antibiotics from wastewater. On the basis of latest literature, we found some new breakthroughs in the degradation mechanisms of antibiotic micropollutants with respect to the AOPs. Therefore, this paper summarizes and highlights the degradation kinetics, pathways and mechanisms of antibiotics degraded by the photo-assisted AOPs, including the UV/O3 process, photo-Fenton technology, and photocatalysis. In the processes, functional groups are attacked by hydroxyl radicals, and major structures are destroyed subsequently, which depends on the classes of antibiotics. Meanwhile, their basic principles, current applications and influencing factors are briefly discussed. The main challenges, prospects, and recommendations for the improvement of photo-assisted AOPs are proposed to better remove antibiotics from wastewater.