化学
溶解
镍
蚀刻(微加工)
吸附
化学工程
电化学
再分配(选举)
解吸
纳米结构
氧气
碳纤维
无机化学
纳米技术
电极
有机化学
材料科学
物理化学
图层(电子)
工程类
政治
复合数
政治学
法学
复合材料
作者
Chong Lin,Xiaojia He,Yi Tan,Shan Wang,Junjie Zou,Chunpei Yan,Peiyan Bi,Guangyuan Ren,Jingyang Tian
出处
期刊:Inorganic Chemistry
[American Chemical Society]
日期:2023-01-24
卷期号:62 (5): 2065-2072
被引量:1
标识
DOI:10.1021/acs.inorgchem.2c03706
摘要
Fe-mediated nickel organic framework nanoarrays (NiFe-MOFs NAs) on carbon cloth were successfully constructed from ultrathin nanosheets via an etching effect. This strategy also combined the dissolution and coordination effect of acidic ligand (2,6-naphthalenedicarboxylic acid, NDC) to a self-sacrificial template of Ni(OH)2 NAs. Benefiting from the strong Fe etching effect, dense and thick brick-like Ni-NDC nanoplates were tailored into loose and ultrathin NiFe-NDC nanosheets with abundant squamous nanostructures, which were still tightly attached to carbon cloth. As a consequence, more coordinatively unsaturated metal sites (CUMSs) that served as active centers were exposed to accelerate oxygen production. Meanwhile, the electronic structure of active Ni centers was modulated by the incorporation of Fe atoms. The charge density redistribution between Ni and Fe ultimately optimized the energy barrier of the adsorption/desorption of oxygenated intermediates, promoting the kinetics for water oxidation.
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