化学
哌嗪
脱氢
烷基
烯烃纤维
芳基
卡宾
有机化学
组合化学
光化学
催化作用
作者
Kokoro Nowaki,Bumpei Maeda,Kei Murakami
标识
DOI:10.1093/chemle/upae024
摘要
Abstract Piperazine represents one of the most important building blocks of pharmaceuticals. Hence, the development of various piperazine derivatives is important. Herein we report photoinduced dehydrogenation of protected piperazines. The reaction proceeded with various alkyl-substituted piperazines. The resulting products have electron-rich olefin moieties that can react with benzyne, carbene, or acyl anhydride.
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