阳极
材料科学
纳米颗粒
电解质
杂原子
电化学
化学工程
金属有机骨架
电极
电子转移
电导率
纳米晶
纳米技术
碳纤维
化学
吸附
光化学
物理化学
有机化学
复合材料
工程类
复合数
戒指(化学)
作者
Miao Yang,Qiu‐Li Ning,Fan Chen,Xing‐Long Wu
标识
DOI:10.1016/j.cclet.2020.07.014
摘要
Metal organic framework (MOF) has been confirmed as the promising precursor to develop the conversion-typed anode materials of sodium-ion batteries (SIBs) because of the tunable structure design and simple functional modification. Here, we prepare the ultrasmall Ni3S2 nanocrystals embedded into N-doped porous carbon nanoparticles using the scalable Ni-MOF as precursor (denoted as Ni3S2@NPC). The ultrasmall size of Ni3S2 can work for accelerated electron/ion transfer to facilitate the electrochemical reaction kinetics. Moreover, the robust conductivity network originated from N-doped porous carbon nanoparticles can not only improve the electron conductivity, but also enhance the electrode integrity and stability of the electrode/electrolyte interface. In addition, the N heteroatoms provide extra Na storage sites. Accordingly, the electrode delivers the obviously competitive capacities and high-power output with respect to the currently reported Ni3S2/C composites. This study provides a scalable and universal strategy to develop the advanced transition metal sulfides for practically feasible SIBs.
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