Electro‐ and Photocatalytic Oxidative Upgrading of Bio‐based 5‐Hydroxymethylfurfural

Abstract Conversion of biomass into biofuels and high value‐added chemicals is a promising strategy to solve the increasingly deteriorating environmental problems caused by fossil energy consumption. The development of efficient technologies and methods is the premise and guarantee to realize the high‐value conversion of biomass. 5‐Hydroxymethylfurfural (HMF), as a versatile biomass platform compound, is generated via dehydration of hexoses (e. g., fructose and glucose) derived from cellulosic biomass. This Review gives an overview of the advances and challenges of electro‐ and photocatalytic oxidation of biomass‐derived HMF to high‐value chemicals such as 2,5‐formylfuran (DFF) and 2,5‐furandicarboxylic acid (FDCA). These strategies and methods for the preparation of high‐value chemicals by electro‐ and photocatalytic oxidation of HMF, coupled with, for example, hydrogen evolution reaction, organic substrate reduction, CO 2 reduction reaction, or N 2 reduction reaction, were summarized and discussed. Moreover, the catalytic efficiency and mechanism of different types of catalysts were also introduced in these conversion systems.