共聚物
衣康酸
高吸水性高分子
高分子化学
壳聚糖
溶解度
过氧化苯甲酰
溶剂
自由基引发剂
材料科学
化学
聚合物
有机化学
聚合
作者
Wafa Al-Mughrabi,Abeer Obaid Hamad Al-Dossary,Abir S. Abdel‐Naby
出处
期刊:Polymers
[MDPI AG]
日期:2022-04-22
卷期号:14 (9): 1707-1707
被引量:5
标识
DOI:10.3390/polym14091707
摘要
Copolymerization of diallylamine (DAA) and itaconic acid (IA) was synthesized using benzoyl peroxide as a free radical initiator, in dioxane as the solvent. The composition of the copolymer was determined by the nitrogen content using Edx. The solubility of the copolymer was also investigated. The water solubility of the synthesized copolymer depends on the comonomers' ratio. The structure of the copolymer was confirmed by 13C-NMR spectroscopy. To increase the water insolubility of the copolymers, and keep their hydrophilicity, the copolymer was allowed to react with chitosan to form a superabsorbent polymeric material (SP). The structure of the synthesized superabsorbent was confirmed using 13C-NMR spectroscopy. The thermal property of the (SP) was also investigated by TGA. The investigation of the chitosan-based superabsorbent, as water-retaining agents, was studied. The results revealed that the superabsorbent polymers exhibited a good swelling ability and salt tolerance.
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