Supported Ru Single Atoms and Clusters on P‐Doped Carbon Nitride as an Efficient Photocatalyst for H2O2 Production

Abstract Photocatalytic H 2 O 2 evolution via two‐electron oxygen reduction is a promising path for renewable and on‐the‐spot H 2 O 2 production compared with the traditional anthraquinone method. However, the efficiency of photocatalytic production of H 2 O 2 is usually very low. Herein, P‐doped carbon nitride loaded with ruthenium single atoms and clusters (Ru atom /P‐CN) is reported as an efficient photocatalyst for H 2 O 2 production. The yield of H 2 O 2 over Ru atom /P‐CN (385.8 mmol g −1 h −1 ) is about 4.3 times higher than that of P‐CN (88.9 mmol g −1 h −1 ) and 3.6 times higher than that of ruthenium nanoparticles loaded P‐CN (105.9 mmol g −1 h −1 ). Further mechanistic study indicates that the presence of Ru in the form of single atoms and clusters not only improves the separation efficiency of photogenerated carriers and inhibits the recombination of photogenerated electron‐hole pairs, but also increases the reactive sites of this catalytic system. This study breaks through people‘s understanding that precious metal loading is not conducive to H 2 O 2 selectivity and provides a new way to prepare low‐metal loading, high‐activity photocatalysts for H 2 O 2 production.