Dynamic multifunctional devices enabled by ultrathin metal nanocoatings with optical/photothermal and morphological versatility

Significance Smart devices characterized by micro-/nanotopographies, such as cracks, wrinkles, folds, etc., have been fabricated for widespread application. Here, with the combination of multiscale hierarchical architecture, ultrathin metal nanocoatings with high optical/photothermal tunability and morphological versatility, and surface/interface engineering, a set of multifunctional devices with multistimuli responsiveness was fabricated. These devices can adapt to external stimuli with reversible and instantaneous responses in optical signals, which include strain-regulated light-scattering properties, photothermal-responsive wrinkled surface coupled with moisture-responsive structural color, and mechanically controllable light-shielding properties. The structural designs that rationally overlay micro-/nanostructured ultrathin nanocoatings with other elements are the key to realize this advanced system, which provides avenues for designing versatile, tunable, and adaptable multifunctional devices.