Characterizing photochemical ageing processes of microplastic materials using multivariate analysis of infrared spectra

>500 spectra) simultaneously discriminated plastic type and extent of photochemical weathering. The magnitude of PCA scores correlated with exposure time and the loadings were consistent with surface chemistry changes including photooxidation. Projecting sunlight and UV-C exposed samples onto this PCA model demonstrated that similar chemical changes occurred, albeit at different rates. The results were compared to the carbonyl index (CI) with similar weathering trends indicating PP weathered at a faster initial rate than LDPE and HDPE. We propose that a multivariate approach is more widely applicable than CI as illustrated by PS, which lacked a stable reference peak. Kinetic analysis of the time series indicated that outdoor weathering occurred 5-12 times slower than the artificial exposure used here, depending on the plastic and the light source employed. The results provide unique insights into weathering processes and the photochemical age of naturally weathered plastics.