Selenium-Infused Ordered Mesoporous Carbon for Room-Temperature All-Solid-State Lithium–Selenium Batteries with Ultrastable Cyclability

Selenium with a similar reaction mechanism with sulfur and a much higher electronic conductivity is considered to be a promising cathode for all-solid-state rechargeable batteries. Herein, selenium-infused ordered mesoporous carbon composites (Se/CMK-3) are successfully prepared by a melt-diffusion method from a ball-milled mixture of Se and CMK-3 (Se-CMK-3). Furthermore, their electrochemical performances are evaluated in all-solid-state lithium–selenium batteries at room temperature. Typically, Li/75%Li 2 S-24%P 2 S 5 -1%P 2 O 5 /Li 10 GeP 2 S 12 /Se/CMK-3 all-solid-state lithium–selenium batteries exhibit high reversible capacity of 488.7 mAh g –1 at 0.05 C after 100 cycles. Even being cycled at 0.5C, it still maintains a discharge capacity of 268.7 mAh g –1 after 200 cycles. The excellent electrochemical performances could be attributed to the enhanced electronic/ionic conductivities and structural integrity with the addition of the CMK-3 matrix.