化学
钴
氢化物
氢
分解
庚烷
动力学
光化学
动能
无机化学
有机化学
物理
量子力学
作者
Ferenc Ungváry,László Markó
标识
DOI:10.1016/s0022-328x(00)80107-2
摘要
The decomposition of cobalt tetracarbonyl hydride to dicobalt octacarbonyl and hydrogen in n-heptane follows the kinetic equation The rate determining step is a reaction between HCo(CO)3 and HCo(CO)4, which does not involve the cobalt-hydrogen bonds. The concentration of HCo(CO)3 in equilibrium with HCo(CO)4 can be calculated.
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